September 14, 2010

1 Comment

In other news: you can even feel the goosebumps

Flexible electronics has been promising a lot for a long time. Organics-based electronics on our clothes and other wonderful gadgets. However, the real potential of the truly bendy stuff hasn’t been compellingly demonstrated for a long time. Sure, you can make wires on a plastic substrate and hope for the best. Which often wasn’t very much in terms of durability and bendability. The situation has only changed in the past four or five years, as nanotechnology devices have been  incorporated onto flexible polymer substrates.

The weight of a fly is sufficient to trigger a signal in the artificial skin pressure sensor realized by Zhenano Bao and colleagues.

The weight of a fly is sufficient to trigger a signal in the artificial skin pressure sensor realized by Zhenano Bao and colleagues. The white PDMS units are visible underneath the fly. Reprinted by permission from Macmillan Publishers Ltd. Nature Materials, advance online publication (2010)

A good example of how far flexible electronics has come are two papers that have just been published in Nature Materials (note: I did not handle either of them as an editor). Both studies realize an “artificial skin” consisting of an array of sensors for position-resolved detection of pressure. As I suspected, both studies received plenty of press coverage, see the articles on Nature News and the BBC website. So here just a few salient points on both of them.

In one of the papers, Ali Javey and colleagues from Berkely use a grid of nanowire transitors to read out signals from a pressure-sensitive rubber membrane. The other study by Stanford’s Zhenan Bao uses PDMS as a pressure-sensitive element that changes its capacity on application of pressure. This information is read out with organic transistors. In the present realisation, Bao’s devices are attached to a silicon substrate, which limits their flexibility.

While for this reason Javey’s arrays are more flexible, with bending radii of 2.5 mm, Bao’s sensors excel with their pressure sensitivity of only 3 Pa. Atmospheric pressure is 101,325 Pa.

The different strategies employed by both groups show the versatility of the field, and the possibility to tailor material properties according to very specific requirements, whether conformability is desired, or sensitivity.

In many news articles on both papers there was a lot of talk about the use of these structures in “artificial skins”. Well, I’d say before we can think in earnest about such uses, there are plenty of practical problems to solve in terms of scalability, durability, stretchability, conformability and so on. At this stage, in my opinion, the flexibility and the sensitivity achieved with these technologies is already exciting enough to give you goosebumps — a sensation that probably could be resolved by the high-sensitivity sensors if they touched your skin.

References:
Mannsfeld, S., Tee, B., Stoltenberg, R., Chen, C., Barman, S., Muir, B., Sokolov, A., Reese, C., & Bao, Z. (2010). Highly sensitive flexible pressure sensors with microstructured rubber dielectric layers Nature Materials DOI: 10.1038/NMAT2834

Takei, K., Takahashi, T., Ho, J., Ko, H., Gillies, A., Leu, P., Fearing, R., & Javey, A. (2010). Nanowire active-matrix circuitry for low-voltage macroscale artificial skin Nature Materials DOI: 10.1038/NMAT2835

September 10, 2010

1 Comment

In other news: self-regenerating solar cells

This week my colleagues at Nature Chemistry landed an impressive scoop, the publication of a paper by Michael Strano and colleagues from MIT on self-regenerating solar cells.

The performance of any kind of solar cell tends to degrade over time. This is particularly the case for organic solar cells, where sunlight can easily destroy the structure of the molecules used. Natural light-harvesting processes have a similar problem, for example during photosynthesis. The way plants solve this problem is through a self-repair mechanism.

Schematic of the regenerating solar cell consisting of light-absorbing proteins, lipid disks and carbon nanotubes. Reprinted by permission from Macmillan Publishers Ltd. Nature Chemistry, advance online publication (2010)

Taking cues from such self-regeneration strategies, Strano and colleagues use a concept that is surprisingly simple. They prepare a solution containing carbon nanotubes, bacterial light-harvesting proteins and discs made from lipid molecules — the structural components that form the membrane of cells. Once the surfactant that keeps all these molecules separate is removed the molecules assemble themselves: the proteins bind to the lipids, which then attach to the carbon nanotubes. No assembly required.

During solar cell operation sunlight is absorbed by the proteins and creates electronic charges that are transported along the carbon nanotubes to the electrical contacts of the solar cell. To regenerate the proteins damaged by the sunlight, surfactant is added again, along with a small quantity of new proteins to replace damaged molecules. This dissolves the structure. But once the surfactant is removed the molecules reassemble, fully repaired.

In the study, the solar cells ran on a 40 hour cycle: 32 hours of operation, followed by 8 hours regeneration. Despite so many hours of regeneration overall cell performance was up by a remarkable 300% in comparison to cells that are not regenerated. And this could be just the beginning. At the moment, as soon as the cells are turned on they lose about 60% efficiency within the first hour or so of operation. Delaying the onset of degradation or finding a more efficient way of regeneration should lead to further enhancements. But who knows, nature may have a solution to this problem, too.

Reference:
Ham, M., Choi, J., Boghossian, A., Jeng, E., Graff, R., Heller, D., Chang, A., Mattis, A., Bayburt, T., Grinkova, Y., Zeiger, A., Van Vliet, K., Hobbie, E., Sligar, S., Wraight, C., & Strano, M. (2010). Photoelectrochemical complexes for solar energy conversion that chemically and autonomously regenerate Nature Chemistry DOI: 10.1038/NCHEM.822

September 8, 2010

1 Comment

Yet more graphene transistors – it’s twins!

Last week I blogged about a Nature paper on graphene transistors with a self-aligned nanowire gate.  Well, as I gather from a blog post by Doug Natelson, largely the same UCLA researchers have now published a paper in Nano Letters that uses a rather similar idea, even though in the latest paper the nanowire gate is made from another material, and it seems the latest transistors are even faster.

However, I am worried about the obviously parallel publication of these two papers. The Nature paper was submitted 23 May, published 1 September. The Nano Letters paper was submitted 16 May and published 3 September.

As Doug says: “Looks like they managed to get two papers in good journals for the price of one technique advance.” And I agree, it looks very much like salami slicing of research results to me. In particular, I like to emphasize that it is editorial policy of Nature journals that editors (like myself) are informed about any related submission made to other journals — see Nature‘s policy on duplicate submissions and plagiarism.

I have not checked this fact with my colleagues and if I would have I could not comment here on my private blog, but I do wonder whether such communication has taken place here. If I were the handling editor, this dual publication would not have been knowingly possible, but others might of course have a different opinion.

Either way, in cases where our policy on duplicate submission is not followed, little can be done if clearly different materials were used, even if a study is based on a similar concept. Apart from increased scrutiny of such authors in future submissions of course.

References:

Liao, L., Bai, J., Cheng, R., Lin, Y., Jiang, S., Qu, Y., Huang, Y., & Duan, X. (2010). Sub-100 nm Channel Length Graphene Transistors Nano Letters DOI: 10.1021/nl101724k

Liao, L., Lin, Y., Bao, M., Cheng, R., Bai, J., Liu, Y., Qu, Y., Wang, K., Huang, Y., & Duan, X. (2010). High-speed graphene transistors with a self-aligned nanowire gate Nature DOI: 10.1038/nature09405